香叶基焦磷酸（GPP）是异戊二烯生物合成途径中的一个中间体。异戊二烯类化合物是一类多样的天然产物，是所有细胞中的必需成分。异戊二烯类化合物是由简单的前体物质异戊二烯焦磷酸（IPP）和二甲基烯丙基焦磷酸（DMAPP）生物合成的。真核生物、真菌和一些革兰氏阳性菌通过甲羟戊酸（MVA）途径产生IPP，而革兰氏阴性菌和一些革兰氏阳性菌则利用非甲羟戊酸途径或2-C-甲基-D-赤藓糖醇-4-磷酸（MEP）途径。GPP是由二甲基烯丙基焦磷酸（DMAPP）和异戊二烯焦磷酸（IPP）在香叶基焦磷酸合酶的催化下缩合形成的。
艾美捷香叶基二磷酸（GPP）：
货号：I-0100
分类：生物化学试剂
筛选：异戊二烯类、异戊二烯焦磷酸
CAS号：104715-14-2
分子式：C10H29N3O7P2
分子量（g/mol）：365.3
纯度：95%
保存条件：-20°C或更低
运输温度：冰胶
香叶基二磷酸（GPP）文献参考：
1. Kuzuyama, T., J. P. Noel, et al. (2005). “Structural basis for the promiscuous biosynthetic prenylation of aromatic natural products.” Nature 435(7044): 983.
展开全文
2. McKay, S. A., W. L. Hunter, et al. (2003). “Insect attack and wounding induce traumatic resin duct development and gene expression of (-)-pinene synthase in Sitka spruce.” Plant Physiol 133(1): 368-78.
3. Schilmiller, A. L., I. Schauvinhold, et al. (2009). “Monoterpenes in the glandular trichomes of tomato are synthesized from a neryl diphosphate precursor rather than geranyl diphosphate.” Proceedings of the National Academy of Sciences 106(26): 10865-10870.
4. Falara, V., Akhtar, T. A., Nguyen, T. T. H., Spyropoulou, E. A., Bleeker, P. M., Schauvinhold, I., … Pichersky, E. (2011). “The tomato terpene synthase gene family.” Plant Physiology, 157(2), 770-789. DOI:10.1104/pp.111.179648
5. Blank, P. N., et al. (2017). “Substitution of Aromatic Residues with Polar Residues in the Active Site Pocket of epi-Isozizaene Synthase Leads to the Generation of New Cyclic Sesquiterpenes.” Biochemistry 56(43): 5798-5811.
6. Rea, K. A., et al. (2019). “Biosynthesis of cannflavins A and B from Cannabis sativa L.” Phytochemistry 164: 162-171.返回搜狐，查看更多